Liquid water isotope measurements report for project FARLAB, run O17_test_03FARLAB, University of Bergen, 21-Aug-2017 22:58:20
Table of Contents
1. Summary |
 |
| Project run ID : | O17_test_03 |
| Project name : | FARLAB |
| Project type : | internal |
| Customer name : | Harald Sodemann (email contact: harald.sodemann@uib.no) |
| Instrument : | HKDS2038 |
| Analysis start : | 07-Aug-2017 15:37:08 |
| Analysis end : | 10-Aug-2017 02:40:05 |
| Number of samples : | 21 |
| Injections/sample : | 15 (max. 15) |
| Number of injections: | 315 |
| Method : | FARLAB_fast |
| Calibration points : | 2 |
| Operator name : | Harald Sodemann (email contact: harald.sodemann@uib.no) |
Averaging over last 3 injections
Table 1: Calibrated measurement values per sample. Standard deviation calculated as standard deviation of the means. Last column provides quality flags as explained in the legend at the bottom.
| Vial | Sample name | dD | d18O | d17O | dxs | e17 | Quality flags |
|---|---|---|---|---|---|---|---|
| 2 | EVAP | 5.02± 0.10 | 5.03± 0.03 | 2.60± 0.05 | -35.24± 0.24 | -52.49± 50.01 | - - - - - - |
| 3 | VATS | -126.32± 0.19 | -16.31± 0.04 | -8.60± 0.04 | 4.14± 0.38 | 43.78± 49.75 | 1 - - - - - |
| 5 | GSM1 | -262.88± 0.27 | -33.01± 0.08 | -17.54± 0.07 | 1.17± 0.68 | 27.30± 82.54 | 1 - - - - - |
| 6 | DI | -50.66± 0.22 | -7.64± 0.01 | -4.01± 0.02 | 10.43± 0.22 | 29.91± 19.49 | 1 - - - - - |
| 7 | SEAII | 1.39± 0.18 | 0.30± 0.05 | 0.17± 0.03 | -1.05± 0.41 | 8.22± 39.70 | 1 - - - - - |
| 9 | EVAP | 5.27± 0.07 | 5.02± 0.01 | 2.59± 0.03 | -34.88± 0.13 | -59.53± 34.77 | - - - - - - |
| 10 | VATS | -126.27± 0.08 | -16.36± 0.03 | -8.64± 0.06 | 4.59± 0.24 | 32.79± 57.86 | 1 - - - - - |
| 12 | GSM1 | -263.07± 0.18 | -33.05± 0.03 | -17.57± 0.04 | 1.32± 0.29 | 17.14± 40.90 | - - - - - - |
| 13 | DI | -50.72± 0.27 | -7.61± 0.02 | -4.00± 0.02 | 10.13± 0.31 | 24.79± 22.86 | 1 - - - - - |
| 14 | SEAII | 1.43± 0.21 | 0.31± 0.06 | 0.17± 0.05 | -1.07± 0.55 | 4.33± 60.68 | - - - - - - |
| 16 | EVAP | 5.25± 0.14 | 5.06± 0.03 | 2.61± 0.03 | -35.20± 0.27 | -61.21± 32.35 | - - - - - - |
| 17 | VATS | -126.27± 0.08 | -16.33± 0.04 | -8.63± 0.04 | 4.40± 0.30 | 30.53± 42.64 | - - - - - - |
| 19 | GSM1 | -262.95± 0.09 | -33.07± 0.01 | -17.58± 0.03 | 1.60± 0.15 | 20.64± 28.28 | - - - - - - |
| 20 | DI | -50.97± 0.08 | -7.69± 0.05 | -4.04± 0.06 | 10.59± 0.38 | 26.46± 69.67 | 1 - - - - - |
| 21 | SEAII | 1.45± 0.10 | 0.35± 0.07 | 0.18± 0.07 | -1.39± 0.57 | -9.84± 78.70 | - - - - - - |
Quality flag legend: (1) Humidity variation, (2) Large humidity correction, (3) Large spectroscopic variability, (4) Large memory effect, (5) Instrument temperature variability, (6) Picarro error codes
Download data file in CSV (comma separated values) format for import in Excel)
Figure 1: Calibrated data for all samples. Calibrated measurements using the 2-point calibration for all of the 15 samples. Black data points denote calibrated values and their standard deviation for d18O, dD, d-excess (permil) and delta17O (permeg) vs. sample number.
Standards:
1. VSMOW2 (dD: 0.00±0.30 permil, d18O: 0.00±0.02 permil, d17O: 0.00±0.06 permil)
2. SLAP2 (dD: -427.50±0.30 permil, d18O: -55.50±0.02 permil, d17O: -29.70±0.04 permil)
Standard VSMOW2 chosen for zero-point and SLAP2 for slope correction.
Standard VSMOW2 at vials 1 8 15
Standard SLAP2 at vials 4 11 18
Figure 2: Instrument drift during run: Drift of the raw measurements of the calibration standard during the run for d18O (top row) and dD (bottom row) for each of the 2 calibration standards. Red solid and dashed lines show the average value of the standard and its standard deviation which has been used for calibration of the entire run period.
All vials included in the analysis
Table 2: Isotope dependency correction per sample. Correction for deviation from reference values at 20000 ppm raw measured water concentration in permil and relative to the measured value (in italics).
| Sample name | H2O | dD | % change | d18O | % change | d17O | % change |
|---|---|---|---|---|---|---|---|
| VSMOW2 | 1439.27± 92.64 | -0.05± 0.00 | -26.71 | -0.01± 0.00 | 3.17 | 0.00± 0.00 | 0.00 |
| EVAP | 1392.33± 138.75 | -0.05± 0.00 | -0.93 | -0.01± 0.00 | -0.24 | 0.00± 0.00 | 0.00 |
| VATS | 1263.93± 148.00 | -0.04± 0.01 | 0.03 | -0.01± 0.00 | 0.06 | 0.00± 0.00 | -0.00 |
| SLAP2 | 1396.87± 112.67 | -0.05± 0.00 | 0.01 | -0.01± 0.00 | 0.02 | 0.00± 0.00 | -0.00 |
| GSM1 | 1338.67± 134.97 | -0.05± 0.00 | 0.02 | -0.01± 0.00 | 0.03 | 0.00± 0.00 | -0.00 |
| DI | 1381.87± 89.59 | -0.05± 0.00 | 0.10 | -0.01± 0.00 | 0.14 | 0.00± 0.00 | -0.00 |
| SEAII | 880.20± 184.31 | -0.03± 0.01 | -1.93 | -0.01± 0.00 | 19.43 | 0.00± 0.00 | 0.00 |
| VSMOW2 | 1172.07± 102.08 | -0.04± 0.00 | -15.79 | -0.01± 0.00 | 2.66 | 0.00± 0.00 | 0.00 |
| EVAP | 1234.67± 113.96 | -0.04± 0.00 | -0.79 | -0.01± 0.00 | -0.21 | 0.00± 0.00 | 0.00 |
| VATS | 1101.67± 72.67 | -0.04± 0.00 | 0.03 | -0.01± 0.00 | 0.05 | 0.00± 0.00 | -0.00 |
| SLAP2 | 1135.00± 108.77 | -0.04± 0.00 | 0.01 | -0.01± 0.00 | 0.02 | 0.00± 0.00 | -0.00 |
| GSM1 | 1181.67± 89.54 | -0.04± 0.00 | 0.02 | -0.01± 0.00 | 0.03 | 0.00± 0.00 | -0.00 |
| DI | 1238.60± 76.75 | -0.04± 0.00 | 0.09 | -0.01± 0.00 | 0.12 | 0.00± 0.00 | -0.00 |
| SEAII | 869.47± 173.03 | -0.03± 0.01 | -1.86 | -0.01± 0.00 | 24.98 | 0.00± 0.00 | 0.00 |
| VSMOW2 | 1124.00± 103.53 | -0.04± 0.00 | -26.96 | -0.01± 0.00 | 2.85 | 0.00± 0.00 | 0.00 |
| EVAP | 1302.73± 109.68 | -0.05± 0.00 | -0.83 | -0.01± 0.00 | -0.22 | 0.00± 0.00 | 0.00 |
| VATS | 1195.33± 87.39 | -0.04± 0.00 | 0.03 | -0.01± 0.00 | 0.06 | 0.00± 0.00 | -0.00 |
| SLAP2 | 1233.33± 155.43 | -0.04± 0.01 | 0.01 | -0.01± 0.00 | 0.02 | 0.00± 0.00 | -0.00 |
| GSM1 | 1196.93± 169.72 | -0.04± 0.01 | 0.02 | -0.01± 0.00 | 0.03 | 0.00± 0.00 | -0.00 |
| DI | 1223.47± 130.24 | -0.04± 0.00 | 0.08 | -0.01± 0.00 | 0.12 | 0.00± 0.00 | -0.00 |
| SEAII | 901.33± 134.05 | -0.03± 0.00 | -1.91 | -0.01± 0.00 | -51.35 | 0.00± 0.00 | 0.00 |
Figure 3: Correction of raw measurements. In sequence, the panels show the correction of the raw isotope measurements for the dependency of the spectroscopy of dD, d18O and d17O on water concentration in the cavity for each injection. The bottom panel shows the deviation of the water concentration from the reference value at 20000ppmv raw water concentration of the used instrument. The correction function was determined from detailed laboratory tests at FARLAB.
| Vial | Injections | Name | TDAS | H2O | H2O_SD | baseline_shift | slope_shift | residuals | ErrorCode |
|---|---|---|---|---|---|---|---|---|---|
| 1 | 1-15 | VSMOW2 | 41.96± 0.08 | 21439.27± 92.64 | 120.29± 5.39 | 76.36± 0.39 | 18.09± 0.08 | 1.84± 0.01 | 000000000000000 |
| 2 | 16-30 | EVAP | 41.88± 0.04 | 21392.33±138.75 | 121.41± 4.27 | 76.12± 0.57 | 17.96± 0.12 | 1.84± 0.02 | 000000000000000 |
| 3 | 31-45 | VATS | 41.90± 0.05 | 21263.93±148.00 | 123.23± 4.35 | 76.17± 0.67 | 18.62± 0.12 | 1.79± 0.02 | 000000000000000 |
| 4 | 46-60 | SLAP2 | 41.82± 0.04 | 21396.87±112.67 | 124.82± 4.50 | 76.04± 0.46 | 20.29± 0.11 | 1.73± 0.02 | 000000000000000 |
| 5 | 61-75 | GSM1 | 41.81± 0.04 | 21338.67±134.97 | 124.43± 3.78 | 76.03± 0.58 | 19.33± 0.17 | 1.77± 0.02 | 000000000000000 |
| 6 | 76-90 | DI | 41.87± 0.04 | 21381.87± 89.59 | 124.79± 4.70 | 76.06± 0.38 | 18.39± 0.15 | 1.82± 0.01 | 000000000000000 |
| 7 | 91-105 | SEAII | 41.85± 0.04 | 20880.20±184.31 | 131.99± 4.68 | 73.99± 0.80 | 17.70± 0.13 | 1.79± 0.02 | 000000000000000 |
| 8 | 106-120 | VSMOW2 | 41.85± 0.05 | 21172.07±102.08 | 126.66± 5.96 | 75.24± 0.41 | 17.92± 0.09 | 1.82± 0.02 | 000000000000000 |
| 9 | 121-135 | EVAP | 41.85± 0.05 | 21234.67±113.96 | 126.68± 4.72 | 75.47± 0.49 | 17.84± 0.11 | 1.83± 0.02 | 000000000000000 |
| 10 | 136-150 | VATS | 41.87± 0.12 | 21101.67± 72.67 | 124.56± 5.08 | 75.59± 0.32 | 18.47± 0.09 | 1.78± 0.01 | 000000000000000 |
| 11 | 151-165 | SLAP2 | 41.81± 0.03 | 21135.00±108.77 | 124.63± 4.07 | 75.03± 0.44 | 20.03± 0.15 | 1.71± 0.02 | 000000000000000 |
| 12 | 166-180 | GSM1 | 41.79± 0.03 | 21181.67± 89.54 | 123.85± 4.80 | 75.36± 0.39 | 19.23± 0.11 | 1.75± 0.01 | 000000000000000 |
| 13 | 181-195 | DI | 41.82± 0.04 | 21238.60± 76.75 | 124.91± 6.53 | 75.44± 0.34 | 18.25± 0.12 | 1.81± 0.01 | 000000000000000 |
| 14 | 196-210 | SEAII | 41.84± 0.04 | 20869.47±173.03 | 126.13± 4.80 | 73.94± 0.74 | 17.72± 0.15 | 1.79± 0.02 | 000000000000000 |
| 15 | 211-225 | VSMOW2 | 41.89± 0.04 | 21124.00±103.53 | 125.04± 5.42 | 74.90± 0.42 | 17.91± 0.11 | 1.82± 0.01 | 000000000000000 |
| 16 | 226-240 | EVAP | 41.99± 0.07 | 21302.73±109.68 | 125.06± 5.85 | 75.70± 0.48 | 17.91± 0.16 | 1.83± 0.02 | 000000000000000 |
| 17 | 241-255 | VATS | 41.94± 0.07 | 21195.33± 87.39 | 125.97± 3.82 | 75.91± 0.39 | 18.53± 0.10 | 1.79± 0.01 | 000000000000000 |
| 18 | 256-270 | SLAP2 | 41.95± 0.11 | 21233.33±155.43 | 126.71± 5.51 | 75.34± 0.66 | 20.12± 0.17 | 1.72± 0.02 | 000000000000000 |
| 19 | 271-285 | GSM1 | 41.91± 0.04 | 21196.93±169.72 | 124.10± 5.21 | 75.40± 0.71 | 19.24± 0.17 | 1.76± 0.02 | 000000000000000 |
| 20 | 286-300 | DI | 41.92± 0.06 | 21223.47±130.24 | 125.92± 4.92 | 75.37± 0.54 | 18.27± 0.14 | 1.81± 0.02 | 000000000000000 |
| 21 | 301-315 | SEAII | 41.89± 0.03 | 20901.33±134.05 | 131.17± 5.40 | 74.01± 0.55 | 17.75± 0.12 | 1.79± 0.02 | 000000000000000 |
Figure 4: Instrument and fitting parameters during the run. Panels show for each injection the data acquisition system (DAS) temperature TDAS, the water concentration, the slope shift, the CH4 concentration,the fitting residuals, and the and H2O slope. Red solid and dashed line indicate the mean and standard deviation for each parameter during the run.
Figure A1: Overview over all injections for vial 1 (VSMOV2). See above for panel description.
Figure A2: Overview over all injections for vial 2 (EVAP). See above for panel description.
Figure A3: Overview over all injections for vial 3 (VATS). See above for panel description.
Figure A4: Overview over all injections for vial 4 (SLAP2). See above for panel description.
Figure A5: Overview over all injections for vial 5 (GSM1). See above for panel description.
Figure A6: Overview over all injections for vial 6 (DI). See above for panel description.
Figure A7: Overview over all injections for vial 7 (SEAII). See above for panel description.
Figure A8: Overview over all injections for vial 8 (VSMOV2). See above for panel description.
Figure A9: Overview over all injections for vial 9 (EVAP). See above for panel description.
Figure A10: Overview over all injections for vial 10 (VATS). See above for panel description.
Figure A11: Overview over all injections for vial 11 (SLAP2). See above for panel description.
Figure A12: Overview over all injections for vial 12 (GSM1). See above for panel description.
Figure A13: Overview over all injections for vial 13 (DI). See above for panel description.
Figure A14: Overview over all injections for vial 14 (SEAII). See above for panel description.
Figure A15: Overview over all injections for vial 15 (VSMOV2). See above for panel description.
Figure A16: Overview over all injections for vial 16 (EVAP). See above for panel description.
Figure A17: Overview over all injections for vial 17 (VATS). See above for panel description.
Figure A18: Overview over all injections for vial 18 (SLAP2). See above for panel description.
Figure A19: Overview over all injections for vial 19 (GSM1). See above for panel description.
Figure A20: Overview over all injections for vial 20 (DI). See above for panel description.