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Interaction of Atoms with Light - Part 4

Quantization of the fields - from the strings of the last lecture
to the electromagnetic field (in Volume V - discretization)

For the particle in electromagnetic field we have used some scans
../2010.11.04/charge-in-elmag-derivation-jpg/
We are working on a new text  (which will be replaced later) is as a pdf here: preliminary_charge_in_elmag.pdf

Quantization of the Electromagnetic Field

We base our discussion on the picture of discretized field - that means that there would be a "countable" system of
eigenmodes for any field system (for N coupled oscillators there are N eigenmodes). For electromagnetic field
there is a total field energy expression (as there would be a total energy expression in terms of displacements
for mechanical oscillators). We see that as it is the E and B are sort of mixed both displacement and momenta
(this gets sort of more understandable if we use the vector potential "in the radiation gauge", then E looks more like
momentum).

The expression for A taken from the litterature contains a mystery constant.

This constant comes from the requirement that the "classical expression" when inserted the expression for A
gives the same result as the algebraic (creation-annihilation) expression with the number of excitation quanta
times hbar omega (in the slide we have a problem with factor 2 - it might originate from a different expression
in SI and Gaussian systems - but the rest of the constant is clearly shown

      E010_Quantized_Elmag_Field.png

       E010_Quantized_Elmag_Field.png

Thus we have an algebraic description - number of photons - based for the electromagnetic fields,
as we need in our "unperturbed" energy operator

Density of Modes

Next topic is "density of modes" or in the Golden rule expression - the density of states
This is always based on discretization - quantization in a large box with edges L x L x L

      D010-density_of_modes_and_states.png

       D010-density_of_modes_and_states.png


      D020-density_of_modes_and_states.png

       D020-density_of_modes_and_states.png


      D030-density_of_modes_and_states.png

       D030-density_of_modes_and_states.png


The atom - field interaction term

The interaction between the atom and the field is obtained from taking into account how a charged particle
gets energy from the field. In classical physics we would also need to consider how the field gets energy
from a moving charge (and there it would be the acceleration which is usually used...)

In the Hamilton-like formulation it will be enough just to take the "action" - the "reaction" should be automatically
included - we do not investigate this in detail - there is enough to do here for the Lagrangian

      E020_Elmag_Field--Particle-Interaction.png

       E020_Elmag_Field--Particle-Interaction.png

Particle in electric and magnetic field - Lagrangian and Hamiltonian - previously shown in
../2010.11.04/charge-in-elmag-derivation-jpg/
We are working on a new text - which has been used in the slides below
a preliminary part (which will be replaced later) is as a pdf here: preliminary_charge_in_elmag.pdf
      L010-Lagrangian_for_particle_in-ELMAG.png

       L010-Lagrangian_for_particle_in-ELMAG.png


      L020-transform-Lagrangian__in-ELMAG.png

       L020-transform-Lagrangian__in-ELMAG.png


      L030-transform-Lagrangian__in-ELMAG.png

       L030-transform-Lagrangian__in-ELMAG.png


Here is the charged particle in electromagnetic field Lagrangian transformed to a Hamiltonian as is usual
in the literature (Bransden and Joachain book)

      L040-Hamiltonian__in-ELMAG.png

       L040-Hamiltonian__in-ELMAG.png


      M010-Schroedinger_in_ELMAG.png

       M010-Schroedinger_in_ELMAG.png


      M020-Interaction_atom_field_linear.png

       M020-Interaction_atom_field_linear.png

This completes all the components for application of the Golden rule -
to evaluate the transition rate

from excited atom to atom in lower energy state and one emitted photon.



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